The phenomenon of cable-shaped indents in the plastic cases of retro systems is one that’s probably painfully familiar to many a collector of such systems. Although in these situations neither side got hot enough to cause any melting – especially while disconnected in storage – it still has that same melted appearance. The real cause here is not heat, but plasticizer migration, as detailed in a recent video by [Run Stop Restored] over on YouTube.
Plasticizers are an additive to many plastics that aim to make it more flexible (‘plastic’), as well as improve other characteristics of the base material, with PVC in particular relying on plasticizers to give it its desired properties for applications where PVC has to be flexible. Here the flexible cable insulation of these devices generally uses PVC, which over time can migrate to other polymers when brought into close contact for extended periods of time.
The – usually ABS – enclosures of e.g. Commodore tape drives as in this video demonstration thus get correspondingly inundated with the same type of plasticizers that ABS is also highly susceptible to. Since in storage the cables tend to be wrapped – tightly – around the device they’re attached to, this results in a solid contact which thus enables this gradual process to work its magic, whether it’s a Commodore datasette or a power supply brick.
Correspondingly the PVC insulation becomes brittle as it loses its plasticizer, with the process sped up by higher environmental temperatures. To prevent this, never wrap a PVC cable around a device, and keep it physically separated from susceptible plastics like ABS as much as reasonably possible. Along with a cool environment this should prevent plasticizer migration from ruining what used to be a pristine case.
This problem is particularly significant for retro gear from the 1980s and thereabouts, before phthalate-free plasticizer alternatives were developed, along with other changes such as more stable formulations that prevent this migration process. Adding a coating can also help, especially for protecting older gear, but flexible PVC in particular should be viewed with suspicion and treated carefully.
This articles is written by : Nermeen Nabil Khear Abdelmalak
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